Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.1/1256
Título: Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry
Autor: Gabelica, Z.
Louati, A.
Borges, C.
Ribeiro, M. F.
Lourenço, J. P.
Murphy, D. M.
Palavras-chave: Co incorporation
Synthesis
Data: 2004
Editora: Elsevier
Citação: Gabeliça, Z.; Louati, A.; Borges, C.; Ribeiro, M.; Lourenço, J. P.; Murphy, D. Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry. In Recent Advances in the Science and Technology of Zeolites and Related Materials Part B. Proceedings of the 14 International Zeolite Conference, 1649-1654, ISBN: 9780444518262. Amsterdam: Elsevier, 2004.
Resumo: Cyclic voltammetric experiments of framework Co(II) ions in three different CoAPO structures have provided evidence for a screening effect created by solvent or template molecules which results in a facile oxidation (and a difficult reduction) of the Co(II) ions incorporated into the most open (the less strained) structures. An apparent contradiction of these findings with respect to theoretical expectations is discussed.
Peer review: yes
URI: http://hdl.handle.net/10400.1/1256
ISBN: 9780444518262
Aparece nas colecções:FCT2-Artigos (em revistas ou actas indexadas)

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