Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.1/4926
Título: Functionalization of mesoporous MCM-41 (Nano)particles: preparation methodologies, role on catalytic features, and dispersion within polyethylene nanocomposites
Autor: Bento, A.
Lourenço, J. P.
Fernandes, A.
Cerrada, María L.
Rosário Ribeiro, M.
Palavras-chave: Nanocomposites
MCM-41
Zirconocene
Ethylene polimerisation
Mesoporous materials
Nanoparticles
Polymerization
Supported catalysis
Data: 2013
Editora: Wiley
Citação: Bento, A.; Lourenço, J. P.; Fernandes, A.; Cerrada, M. L.; Rosário Ribeiro, M.Functionalization of Mesoporous MCM-41 (Nano)particles: Preparation Methodologies, Role on Catalytic Features, and Dispersion Within Polyethylene Nanocomposites, ChemCatChem, 5, 4, 966-976, 2013.
Resumo: MCM-41 micro- and nanoparticles are prepared and functionalized with silane coupling agents. These pristine and silane-decorated mesoporous MCM-41s are further used in the synthesis of MCM-41/ethylene nanocomposites by in situ polymerization, utilizing either supported or non-supported catalytic systems. The catalytic behavior of those systems is discussed, taking into consideration the effects of the particle size, surface characteristics, and functionalization. The results have shown that the initial surface state of MCM-41 is of paramount importance to achieve high catalytic activity if a polymerization catalyst is to be supported. Functionalization changes the surface chemistry, thus, a positive or negative effect may be observed, depending on the previous features of the surface. The particle size of MCM-41 and its functionalization affect its final dispersion within the polymeric matrix, this distribution is evaluated by SEM, TEM, and microhardness measurements.
Peer review: yes
URI: http://hdl.handle.net/10400.1/4926
DOI: http://dx.doi.org/10.1002/cctc.201200639
ISSN: 1867-3880
Aparece nas colecções:FCT2-Artigos (em revistas ou actas indexadas)

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