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Gomes, Henrique Leonel

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  • Confocal scanning raman spectroscopy (CSRS) of an operating organic light-emitting diode
    Publication . Paez-Sierra, B. A.; Gomes, Henrique L.
    Organic molecules with semiconducting properties are becoming nowadays core of the organic-based electronic era. Although organic light emitting diodes (OLEDs) have already matured for commercial applications, they still require longer device lifetimes. Some of the long-standing challenges in OLED technology relay on degradation and failure mechanisms. Several authors observed that degradation and subsequent damage of OLEDs is accompanied by formation of dark non-emissive spots [1-2]. Implementation of the confocal scanning Raman spectroscopy (CSRS) measurements helps to understand the chemistry, physics of OLEDs and moreover to have better confidence on their quality assurance.
  • Doping distribution of an operating organic light-emitting diode: a raman map analysis
    Publication . Paez-Sierra, B. A.; Gomes, Henrique L.; Rangel-Kuoppa, V.T.
    We present confocal Raman spectroscopy (CSRS) maps of Poly(9,9-dioctylfluorene) (PFO)-based organic light emitting diode under operation. The CSRS analysis of the OLEDs was performed in normal room conditions. The non-emissive spots presented higher Raman intensity and broadening of the vibrational bands in comparison with the luminescent ones. The phenomenon is associated with an increase in the PFO - * absorption band and hence modification of the PFO doping which becomes favorable to the excitation wavelength, thus the Raman spectrum is enhanced. To the authors’ knowledge this image technique had been missed for the OLED technology.