Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.1/6621
Título: Influence of the metal center on the morphology of coordination compounds thin films
Autor: Toffolo, F.
Brinkmann, M.
Greco, O.
Biscarini, F.
Taliani, C.
Gomes, Henrique L.
Aiello, I.
Ghedini, M.
Data: 1999
Editora: Elsevier Science
Resumo: Thin film morphology of tris-(8-hydroxyquinolate) aluminium (III) (Alq3) and bis-(8-hydroxyquinolate) oxovanadium (IV) (VOq2) are compared. Alq3 films deposited onto mica at 300K look almost featureless, but dendrimers or randomly distributed needle-shaped crystallites appear as a consequence of crystallization in time. We show that a possible origin of this process is exposure to solvent vapors. On the other hand, VOq2 films retain their textured morphology as thickness increases because of stabilizing intermolecular interactions between vanadyl groups.
Peer review: yes
URI: http://hdl.handle.net/10400.1/6621
DOI: https://dx.doi.org/10.1016/S0379-6779(98)01415-5
ISSN: 0379-6779
Aparece nas colecções:FCT2-Artigos (em revistas ou actas indexadas)

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