Browsing by Author "Emslie, Steven D."
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- Mercury in archaeological human bone: biogenic or diagenetic?Publication . Emslie, Steven D.; Alderman, Audrey; McKenzie, Ashley; Brasso, Rebecka; Taylor, Alison R.; Molina Moreno, Maria; Cambra-Moo, Oscar; Gonzalez Martin, Armando; Silva, Ana Maria; Valera, António Carlos; Garcia Sanjuan, Leonardo; Vijande Vila, EduardoWe investigated mercury (Hg) in human bone from archaeological sites in the Iberian Peninsula where the cultural use of cinnabar (HgS) as a pigment, offering or preservative in burial practices has been documented from the 4th to 2nd millennia cal B.C. (Late Neolithic, Copper Age and Bronze Age). Previous analyses have shown high levels of total mercury (THg) in human bone at numerous Neolithic and Chalcolithic sites in this region, but the question remains if this mercury entered the bones via diagenetic processes in the soil, especially where cinnabar powder and paint was found associated with the burials, or if it entered the bone via biogenic pathways from exposure to mercury from using cinnabar in life. We analyzed the humerus, femur, and tibia from a total of 30 individual burials from four Neolithic to Bronze Age sites in Iberia and found low to high values of THg in these bones, with the humerus showing significantly more THg concentrations than other skeletal elements when the THg was greater than 1 ppm. This pattern of Hg deposition in skeletal material from different sites and ages strongly suggests a biogenic origin for the mercury. In addition, absence of detectable Hg in bones with high to low values of THg using SEM EDS analysis further discounts diagenetic intrusion of Hg or cinnabar particles into the bone from the soil. It is likely that greater stress and bone remodeling rates from use of heavy tools and other activities in life are responsible for higher THg in the humerus than other skeletal elements, but additional research is needed to verify this.
- The use and abuse of cinnabar in Late Neolithic and Copper Age IberiaPublication . Emslie, Steven D.; Silva, Ana Maria; Valera, António Carlos; Vijande Vila, Eduardo; Melo, Linda; Curate, Francisco; Fidalgo, Daniel; Inácio, Nuno; Molina Moreno, María; Cambra‐Moo, Oscar; González Martín, Armando; Barroso‐Bermejo, Rosa; Montero Artús, Raquel; García Sanjuán, LeonardoIn this study, total mercury (THg) was analyzed in archaeological human bone from 23 sites dating to between the Middle Neolithic and the Antiquity. A total of 370 individuals from individual or collective burials was sampled, mostly using cortical bone from the humerus. These individuals were recovered from over 50 different funerary structures ranging from tholoi, pits, caves, and hypogea. Although cinnabar (HgS) is a likely cause of mercury poisoning and toxicity for people exposed to this mineral from mining or use as a paint or pigment, not all sites investigated here had cinnabar associated with the burials or other excavated areas. We found unusual levels of THg in many of the sampled individuals that we assume were caused by exposure to cinnabar in life, and not by diagenetic processes or other exposures to mercury such as through diet, which would only cause negligible accumulation of THg in bone. Our data, based on the largest sampling ever undertaken on contamination of human bone through archaeological evidence, provide a baseline for additional research on cinnabar and its use in Prehistory. Moderate to high levels of THg in human bone are mainly associated with societies dating from the second half of the 4th to late 3rd millennia B.C. (Late Neolithic to Middle Chalcolithic) in southern Iberia. By the Late Chalcolithic and Early Bronze Age, the use of cinnabar decreased significantly and became minimal or absent. The use and abuse of cinnabar appears to have been pervasive throughout the above-mentioned period and particularly between c. 2900-2300 B.C. This occurred in connection with the high symbolic and probably sacred value of the substance, which was sought after, traded, and extensively used in a variety of rituals and social practices.