Browsing by Issue Date, starting with "2023-07-24"
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- Eco-friendly methods for extraction and modification of cellulose: an overviewPublication . Magalhães, Solange; Fernandes, Catarina; Pedrosa, Jorge F. S.; Alves, Luís; Medronho, Bruno; Ferreira, Paulo J. T.; Rasteiro, Maria da GraçaCellulose is the most abundant renewable polymer on Earth and can be obtained from several different sources, such as trees, grass, or biomass residues. However, one of the issues is that not all the fractionation processes are eco-friendly and are essentially based on cooking the lignocellulose feedstock in a harsh chemical mixture, such as NaOH + Na2S, and water, to break loose fibers. In the last few years, new sustainable fractionation processes have been developed that enable the obtaining of cellulose fibers in a more eco-friendly way. As a raw material, cellulose’s use is widely known and established in many areas. Additionally, its products/derivatives are recognized to have a far better environmental impact than fossil-based materials. Examples are textiles and packaging, where forest-based fibers may contribute to renewable and biodegradable substitutes for common synthetic materials and plastics. In this review, some of the main structural characteristics and properties of cellulose, recent green extraction methods/strategies, chemical modification, and applications of cellulose derivatives are discussed.
- Surface displacement of Hurd Rock glacier from 1956 to 2019 from historical aerial frames and satellite imagery (Livingston Island, Antarctic Peninsula)Publication . Prates, Gonçalo; Vieira, GonçaloIn the second half of the 20th century, the western Antarctic Peninsula recorded the highest mean annual air temperature rise in the Antarctic. The South Shetland Islands are located about 100 km northwest of the Antarctic Peninsula. The mean annual air temperature at sea level in this Maritime Antarctic region is close to −2 °C and, therefore, very sensitive to permafrost degradation following atmospheric warming. Among geomorphological indicators of permafrost are rock glaciers found below steep slopes as a consequence of permafrost creep, but with surficial movement also generated by solifluction and shallow landslides of rock debris and finer sediments. Rock glacier surface velocity is a new essential climate variable parameter by the Global Climate Observing System, and its historical analysis allows insight into past permafrost behavior. Recovery of 1950s aerial image stereo-pairs and structure-from-motion processing, together with the analysis of QuickBird 2007 and Pleiades 2019 high-resolution satellite imagery, allowed inferring displacements of the Hurd rock glacier using compression ridge-and-furrow morphology analysis over 60 years. Displacements measured on the rock glacier surface from 1956 until 2019 were from 7.5 m to 22.5 m and surface velocity of 12 cm/year to 36 cm/year, measured on orthographic images, with combined deviation root-mean-square of 2.5 m and 2.4 m in easting and northing. The inferred surface velocity also provides a baseline reference to assess today’s displacements. The results show patterns of the Hurd rock glacier displacement velocity, which are analogous to those reported within the last decade, without being possible to assess any displacement acceleration.