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Tetrapyridinium mu-oxido-di-mu-sulfato-bis[chloridodioxidomolybdate(VI)]

2010-08Journal article Open Access
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dc.contributor.authorFernandes, José A.
dc.contributor.authorGomes, Ana C.
dc.contributor.authorFigueiredo, Sonia
dc.contributor.authorS. Gago
dc.contributor.authorLopes, Andre D.
dc.contributor.authorMartyn Pillinger
dc.contributor.authorRibeiro-Claro
dc.contributor.authorGonçalves, Isabel S.
dc.contributor.authorFilipe A. Almeida Paz
dc.date.accessioned2018-12-07T14:52:42Z
dc.date.available2018-12-07T14:52:42Z
dc.date.issued2010-08
dc.description.abstractThe title salt, (C(5)H(6)N)(4)[Mo(2)Cl(2)O(5)(SO(4))(2)], comprises four pyridinium cations for each [(MoClO(2))(2)(mu-O)(mu-SO(4))(2)]4- anionic unit. The asymmetric unit consists of three aggregates of the empirical formula. The tetraanionic bimetallic molybdenum(VI) cluster is unprecedented and contains two sulfate and one oxide bridges. This structure constitutes the first example of a non-polymeric compound with terminal oxide, sulfate and halide ligands bonded to the same metal. The hydrogen bonds connecting the pyridinium cations to the molybdenum clusters are diverse, varying from strong and directional interactions to bifurcated bonds with a subsequent loss of directionality.
dc.description.sponsorshipFundacao para a Ciencia e a Tecnologia (FCT, Portugal) [SFRH/BPD/63736/2009, SFRH/BPD/25269/2005, SFRH/BD/45116/2008]; Associated Laboratory CICECO
dc.description.versioninfo:eu-repo/semantics/publishedVersion
dc.identifier.doi10.1107/S1600536810028254
dc.identifier.issn1600-5368
dc.identifier.urihttp://hdl.handle.net/10400.1/11170
dc.language.isoeng
dc.peerreviewedyes
dc.publisherWiley-Blackwell Publishing, Inc
dc.relationNANOCABLES: COORDINATION POLYMERS INCLUDED IN CYCLODEXTRINS
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectCrystal-structures
dc.subjectComplexes
dc.titleTetrapyridinium mu-oxido-di-mu-sulfato-bis[chloridodioxidomolybdate(VI)]
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleNANOCABLES: COORDINATION POLYMERS INCLUDED IN CYCLODEXTRINS
oaire.awardURIinfo:eu-repo/grantAgreement/FCT//SFRH%2FBPD%2F63736%2F2009/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F25269%2F2005/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F45116%2F2008/PT
oaire.citation.endPageU1354
oaire.citation.startPageM1005
oaire.citation.titleActa Crystallographica Section E: Structure Reports Online
oaire.citation.volume66
oaire.fundingStreamSFRH
oaire.fundingStreamSFRH
person.familyNameFernandes
person.familyNameGago
person.familyNameD. Lopes
person.familyNamePillinger
person.familyNameRibeiro-Claro
person.familyNameGonçalves
person.familyNameAlmeida Paz
person.givenNameJosé
person.givenNameSandra
person.givenNameAndré
person.givenNameMartyn
person.givenNamePaulo
person.givenNameIsabel
person.givenNameFilipe
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person.identifier.ridB-8073-2008
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project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccess
rcaap.typearticle
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