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A single drop histamine sensor based on AuNPs/MnO2 modified screen-printed electrode

dc.contributor.authorKnezevic, Sara
dc.contributor.authorOgnjanovic, Milos
dc.contributor.authorNedic, Nemanja
dc.contributor.authorMariano, José
dc.contributor.authorMilanovic, Zorana
dc.contributor.authorPetkovic, Branka
dc.contributor.authorAntic, Bratislav
dc.contributor.authorDjuric, Sanja Vranjes
dc.contributor.authorStankovic, Dalibor
dc.date.accessioned2021-06-24T11:35:33Z
dc.date.available2021-06-24T11:35:33Z
dc.date.issued2020-06
dc.description.abstractIn order to ensure high food quality, one of the prime importance is the detection and quantification of histamine, well known marine food poison. In this work, we constructed novel electrochemical biosensor for the detection of histamine based on gold nanoparticles decorated on manganese dioxide (Au/MnO2) and used for modification of screen-printed carbon electrode (Au/MnO2@SPCE). The constructed sensor was then used for the estimation of histamine content in a single drop. Materials used in this study were synthesized and characterized using HR-TEM, XRPD and electrochemical methods. The amperometric detection method was optimized and, under selected operating parameters (supporting electrolyte pH 6, working potential of 1 V), the proposed sensor possesses linear working range from 0.3 mu M to 5.1 mu M, with a detection limit of 0.08 mu M. The effect of selected interferences was investigated and it was found that the developed approach offers accurate, precise, selective, fast and reproducible quantification of histamine using only one drop of the sample. In the end, this work stands as a proof-of-concept of the modified electrodes and electrochemical detection as a promising and prospective approach for the applications in real-time monitoring of the food quality.
dc.description.sponsorshipMinistry of Education, Science and Technological Development of the Republic of Serbia, through Eureka project [E!13303]
dc.description.versioninfo:eu-repo/semantics/publishedVersion
dc.identifier.doi10.1016/j.microc.2020.104778
dc.identifier.issn0026-265X
dc.identifier.urihttp://hdl.handle.net/10400.1/16472
dc.language.isoeng
dc.peerreviewedyes
dc.publisherElsevier
dc.subjectSingle drop detection
dc.subjectElectrochemistry
dc.subjectSensors
dc.subjectScreen-printed electrode
dc.subjectHistamine
dc.subjectMarine food quality
dc.subject.otherChemistry
dc.titleA single drop histamine sensor based on AuNPs/MnO2 modified screen-printed electrode
dc.typejournal article
dspace.entity.typePublication
oaire.citation.startPage104778
oaire.citation.titleMicrochemical Journal
oaire.citation.volume155
person.familyNameMariano
person.givenNameJosé
person.identifier.ciencia-idDE19-7D9D-00D0
person.identifier.orcid0000-0002-8480-617X
person.identifier.ridO-5252-2018
person.identifier.scopus-author-id12647832000
rcaap.rightsrestrictedAccess
rcaap.typearticle
relation.isAuthorOfPublication16ee0cfc-3dd4-40fa-8401-b435aa41ef7d
relation.isAuthorOfPublication.latestForDiscovery16ee0cfc-3dd4-40fa-8401-b435aa41ef7d

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