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Diels–Alder reactions of 3-(1H-tetrazol-5-yl)-nitrosoalkenes: synthesis of functionalized 5-(substituted)-1H-tetrazoles
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Orientador(es)
Resumo(s)
A general route to 1,2-oxazines and open chain oximes bearing a 1H-tetrazolyl substituent via DielseAlder
reaction of 3-(tetrazol-5-yl)-nitrosoalkenes is reported. It was also demonstrated that reduction of these
adducts followed by deprotection of the tetrazolyl group give 5-(1-aminoalkyl)-1H-tetrazoles, a-amino
acid analogues.
Descrição
Palavras-chave
Cicloadição Diels-Alder Heterocycles
Contexto Educativo
Citação
Lopes, Susana M.M.; Palacios, Francisco; Lemos, A.; Melo, Teresa M.V.D.Pinho e. Diels–Alder reactions of 3-(1H-tetrazol-5-yl)-nitrosoalkenes: synthesis of functionalized 5-(substituted)-1H-tetrazoles. Tetrahedron, 67, 46, 8902-8909, 2011.