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Influence of the metal center on the morphology of coordination compounds thin films

dc.contributor.authorToffolo, F.
dc.contributor.authorBrinkmann, M.
dc.contributor.authorGreco, O.
dc.contributor.authorBiscarini, F.
dc.contributor.authorTaliani, C.
dc.contributor.authorGomes, Henrique L.
dc.contributor.authorAiello, I.
dc.contributor.authorGhedini, M.
dc.date.accessioned2015-06-26T14:18:45Z
dc.date.available2015-06-26T14:18:45Z
dc.date.issued1999
dc.description.abstractThin film morphology of tris-(8-hydroxyquinolate) aluminium (III) (Alq3) and bis-(8-hydroxyquinolate) oxovanadium (IV) (VOq2) are compared. Alq3 films deposited onto mica at 300K look almost featureless, but dendrimers or randomly distributed needle-shaped crystallites appear as a consequence of crystallization in time. We show that a possible origin of this process is exposure to solvent vapors. On the other hand, VOq2 films retain their textured morphology as thickness increases because of stabilizing intermolecular interactions between vanadyl groups.
dc.identifier.doihttps://dx.doi.org/10.1016/S0379-6779(98)01415-5
dc.identifier.issn0379-6779
dc.identifier.otherAUT: HGO00803;
dc.identifier.urihttp://hdl.handle.net/10400.1/6621
dc.language.isoeng
dc.peerreviewedyes
dc.publisherElsevier Science
dc.relation.isbasedonP-001-4GY
dc.titleInfluence of the metal center on the morphology of coordination compounds thin films
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceMontpellier, France
oaire.citation.endPage141
oaire.citation.startPage140
oaire.citation.titleSynthetic Metals
oaire.citation.titleInternational Conference on Science and Technology of Synthetic Metals (ICSM 98)
oaire.citation.volume101
person.familyNameGomes
person.givenNameHenrique Leonel
person.identifier.orcid0000-0003-3664-4740
person.identifier.scopus-author-id7005305880
rcaap.rightsrestrictedAccess
rcaap.typearticle
relation.isAuthorOfPublication6da677b9-927f-423d-8657-448a0dccb67c
relation.isAuthorOfPublication.latestForDiscovery6da677b9-927f-423d-8657-448a0dccb67c

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