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Perspectives on the Lindman Hypothesis and cellulose interactions

dc.contributor.authorNorgren, Magnus
dc.contributor.authorCosta, Carolina
dc.contributor.authorAlves, Luís
dc.contributor.authorEivazi, Alireza
dc.contributor.authorDahlström, Christina
dc.contributor.authorSvanedal, Ida
dc.contributor.authorEdlund, Håkan
dc.contributor.authorMedronho, Bruno
dc.date.accessioned2023-05-26T15:23:03Z
dc.date.available2023-05-26T15:23:03Z
dc.date.issued2023-05-21
dc.date.updated2023-05-26T13:21:30Z
dc.description.abstractIn the history of cellulose chemistry, hydrogen bonding has been the predominant explanation when discussing intermolecular interactions between cellulose polymers. This is the general consensus in scholarly textbooks and in many research articles, and it applies to several other biomacromolecules’ interactions as well. This rather unbalanced description of cellulose has likely impacted the development of materials based on the processing of cellulose—for example, via dissolution in various solvent systems and regeneration into solid materials, such as films and fibers, and even traditional wood fiber handling and papermaking. In this review, we take as a starting point the questioning of the general description of the nature of cellulose and cellulose interactions initiated by Professor Björn Lindman, based on generic physicochemical reasoning about surfactants and polymers. This dispute, which became known as “the Lindman hypothesis”, highlights the importance of hydrophobic interactions in cellulose systems and that cellulose is an amphiphilic polymer. This paper elaborates on Björn Lindman’s contribution to the subject, which has caused the scientific community to revisit cellulose and reconsider certain phenomena from other perspectives.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifierdoi: 10.3390/molecules28104216
dc.identifier.citationMolecules 28 (10): 4216 (2023)pt_PT
dc.identifier.doi10.3390/molecules28104216pt_PT
dc.identifier.issn1420-3049
dc.identifier.urihttp://hdl.handle.net/10400.1/19627
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherMDPIpt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectCellulosept_PT
dc.subjectAmphiphilicitypt_PT
dc.subjectIntermolecular interactionspt_PT
dc.subjectDissolutionpt_PT
dc.subjectRegenerationpt_PT
dc.subjectEmulsificationpt_PT
dc.subjectComposite materialspt_PT
dc.titlePerspectives on the Lindman Hypothesis and cellulose interactionspt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.issue10pt_PT
oaire.citation.startPage4216pt_PT
oaire.citation.titleMoleculespt_PT
oaire.citation.volume28pt_PT
person.familyNameMedronho
person.givenNameBruno
person.identifier.ciencia-id6918-9AB3-8D22
person.identifier.orcid0000-0003-0972-1739
person.identifier.ridP-5927-2014
person.identifier.scopus-author-id9940656700
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication4c03571a-93da-4504-8acf-c74326449852
relation.isAuthorOfPublication.latestForDiscovery4c03571a-93da-4504-8acf-c74326449852

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