Publication
A latent reaction in a model gfp chromophore revealed upon confinement: photohydroxylation of ortho-halo benzylidene-3-methylimidazolidiones via an electrocylization process
| dc.contributor.author | Samanta, Shampa R. | |
| dc.contributor.author | Silva, José P. da | |
| dc.contributor.author | Baldridge, Anthony | |
| dc.contributor.author | Tolbert, Laren M. | |
| dc.contributor.author | Ramamurthy, V. | |
| dc.date.accessioned | 2015-06-22T14:13:50Z | |
| dc.date.available | 2015-06-22T14:13:50Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Excited state behavior of halogen substituted model GFP chromophores was investigated in an acetonitrile solution and in a confined environment provided by an octa acid capsule in water. Of the ortho, meta, and para halogen substituted GFP chromophores only the ortho compounds gave a new product resulting from an unprecedented photosubstitution of halogens by the hydroxyl group. This unusual reaction highlights the importance of confined spaces in bringing about some unattainable photoreactions. | |
| dc.identifier.doi | https://dx.doi.org/10.1021/ol5013058 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.uri | http://hdl.handle.net/10400.1/6559 | |
| dc.language.iso | eng | |
| dc.peerreviewed | yes | |
| dc.publisher | American Chemical Society | |
| dc.relation.isbasedon | P-009-M03 | |
| dc.title | A latent reaction in a model gfp chromophore revealed upon confinement: photohydroxylation of ortho-halo benzylidene-3-methylimidazolidiones via an electrocylization process | |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 3307 | |
| oaire.citation.issue | 12 | |
| oaire.citation.startPage | 3304 | |
| oaire.citation.title | Organic Letters | |
| oaire.citation.volume | 16 | |
| person.familyName | Silva | |
| person.givenName | José Paulo da | |
| person.identifier.ciencia-id | 3413-C4F4-73F7 | |
| person.identifier.orcid | 0000-0002-6458-7328 | |
| person.identifier.rid | A-4606-2008 | |
| person.identifier.scopus-author-id | 7201733236 | |
| rcaap.rights | restrictedAccess | |
| rcaap.type | article | |
| relation.isAuthorOfPublication | e2004fa2-a47d-44b0-b11c-fc95fe51cbf9 | |
| relation.isAuthorOfPublication.latestForDiscovery | e2004fa2-a47d-44b0-b11c-fc95fe51cbf9 |
Files
Original bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- A latent reaction in a model gfp chromophore revealed upon confinement.pdf
- Size:
- 830.07 KB
- Format:
- Adobe Portable Document Format