Ethyl 2-(Diisopropoxyphosphoryl)-2H-azirine-3-carboxylate: reactions with Nucleophilic 1,3-Dienes

Lemos, A.; Alves, Maria José Chão

http://hdl.handle.net/10400.1/1042

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Authors

Lemos, A.

Alves, Maria José Chão

Abstract(s)

Ethyl 2-(diisopropoxyphosphoryl)-2H-azirine-3-carboxylate, the first example of an azirine bearing simultaneously ester and phosphonate groups was generated in situ and reacted with a number of 1,3-dienes. Cycloadducts or their ensuing rearranged products were isolated in moderate yields.

Keywords

Azirinas Cicloadição Diels-Alder Heterociclos Aminoacidos

URI

http://hdl.handle.net/10400.1/1042

Citation

Lemos, A.; Alves, Maria José Chão. Ethyl 2-(Diisopropoxyphosphoryl)-2H-azirine-3-carboxylate: reactions with Nucleophilic 1,3-Dienes. Synthesis, 19, 3263-3266, 2009.