Publication
A kinetic investigation of the thermal rearrangement of allyloxytetrazoles to N-allyltetrazolones
| dc.contributor.author | Cristiano, Maria Lurdes Santos | |
| dc.contributor.author | Johnstone, Robert A. W. | |
| dc.date.accessioned | 2014-06-09T13:20:02Z | |
| dc.date.available | 2014-06-09T13:20:02Z | |
| dc.date.issued | 1997 | |
| dc.date.updated | 2014-06-05T09:17:55Z | |
| dc.description.abstract | The mechanism of the thermal rearrangement of 1-aryl-5-allyloxytetrazoles 1 to give 1-aryl-4-allyltetrazolones 2 in very high yield has been investigated through kinetic studies in one polar and one less polar solvent. The results suggest mainly a concerted [3,3] sigmatropic process, in which a partially positively charged allyl group migrates from oxygen to nitrogen, similar to the polar transition state found in the Claisen rearrangement. | por |
| dc.identifier.citation | Cristiano, M. Lurdes S.; Johnstone, Robert A. W. A kinetic investigation of the thermal rearrangement of allyloxytetrazoles to N-allyltetrazolones, Journal of the Chemical Society, Perkin Transactions 2, 3, 489-494, 1997. | por |
| dc.identifier.issn | 0300-9580 | |
| dc.identifier.other | AUT: MCR00716; | |
| dc.identifier.uri | http://hdl.handle.net/10400.1/4256 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | Chemical Society | por |
| dc.relation.publisherversion | View Article Online | por |
| dc.title | A kinetic investigation of the thermal rearrangement of allyloxytetrazoles to N-allyltetrazolones | por |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 494 | por |
| oaire.citation.issue | 3 | por |
| oaire.citation.startPage | 489 | por |
| oaire.citation.title | Perkin Transactions 2 | por |
| oaire.citation.volume | 2 | por |
| person.familyName | Cristiano | |
| person.givenName | Maria de Lurdes | |
| person.identifier.ciencia-id | E411-6006-5A01 | |
| person.identifier.orcid | 0000-0002-9447-2855 | |
| person.identifier.rid | G-2345-2012 | |
| person.identifier.scopus-author-id | 9238724800 | |
| rcaap.rights | restrictedAccess | por |
| rcaap.type | article | por |
| relation.isAuthorOfPublication | b16751a6-748e-44b0-9c59-058cbd5b2cc3 | |
| relation.isAuthorOfPublication.latestForDiscovery | b16751a6-748e-44b0-9c59-058cbd5b2cc3 |
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