Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate

Lemos, A.; Guimaraes, Emanuel; Fortes, Gil; Alves, Maria José Chão

http://hdl.handle.net/10400.1/1023

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Authors

Lemos, A.

Guimaraes, Emanuel

Fortes, Gil

Alves, Maria José Chão

Abstract(s)

The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.

Keywords

Azirinas Heterocycles Intermolecular radical addition Triethylborane Alfa-aminoesters

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http://hdl.handle.net/10400.1/1023

Citation

Synlett, 10, 1403-1406, 2003.

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Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate

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