Unusual reactivity of selenoboranes towards epoxides: New selective routes to beta- hydroxyselenides and allylalcohols

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dc.contributor.author	Cravador, A.
dc.contributor.author	Krief, A.
dc.date.accessioned	2015-06-15T09:15:56Z
dc.date.available	2015-06-15T09:15:56Z
dc.date.issued	1981
dc.description.abstract	Selenoboranes react with terminal, α, β-di- and trisubstituted epoxides to produce β-hydroxyselenides (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α, β-bisubstituted epoxides: the cis epoxide being much more reactive.	pt_PT
dc.identifier.doi	https://dx.doi.org/10.1016/S0040-4039(01)92941-7
dc.identifier.issn	0040-4039
dc.identifier.other	AUT: ACR00659;
dc.identifier.uri	http://hdl.handle.net/10400.1/6162
dc.language.iso	eng
dc.peerreviewed	yes
dc.publisher	Pergamon- Elsevier Science, Ltd
dc.relation.isbasedon	P-009-32Z
dc.title	Unusual reactivity of selenoboranes towards epoxides: New selective routes to beta- hydroxyselenides and allylalcohols
dc.type	journal article
dspace.entity.type	Publication
oaire.citation.endPage	2494
oaire.citation.startPage	2491
oaire.citation.title	Tetrahedron Letters
oaire.citation.volume	22
person.familyName	Cravador
person.givenName	Alfredo
person.identifier.orcid	0000-0002-9831-9815
person.identifier.rid	K-7247-2012
person.identifier.scopus-author-id	6602537257
rcaap.rights	restrictedAccess
rcaap.type	article
relation.isAuthorOfPublication	8c84a9e6-6b7f-4b50-93a2-152c85901722
relation.isAuthorOfPublication.latestForDiscovery	8c84a9e6-6b7f-4b50-93a2-152c85901722

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