Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride

Fernandes, José A.; Gomes, Ana C.; Figueiredo, Sonia; Gago, Sandra; Ribeiro-Claro, Paulo J. A.; Gonçalves, Isabel S.; Almeida Paz, Filipe A.

http://hdl.handle.net/10400.1/11474

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Authors

Ribeiro-Claro, Paulo J. A.

Gonçalves, Isabel S.

Almeida Paz, Filipe A.

Abstract(s)

In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H center dot center dot center dot Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octahedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.