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Using the reactions O+H2 → OH+H to explore the importance of the atomic quantum states on chemical kinetics and reaction dynamics

2015-06Journal article Open Access
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dc.contributor.authorRio, Carolina
dc.contributor.authorBrandão, J.
dc.contributor.authorWang, Wenli
dc.date.accessioned2015-06-30T18:26:34Z
dc.date.available2015-06-30T18:26:34Z
dc.date.issued2015-06
dc.description.abstractThe O + H2 reaction is a particular example to alert the importance of a clear definition of the quantum state of an atom when referring to a chemical reaction. In its ground state, O (3P), the oxygen atom reacts with H2 through an energy barrier with small rate constant. In contrast, when the oxygen atom is in its first excited state, O (1D), the reaction O + H2 occurs without energy barrier and the rate constant is seven orders of magnitude higher. The dynamic behaviour of this reaction depends also on the quantum state of the oxygen atom.por
dc.identifier.doihttp://dx.doi.org/10.13189/ujc.2015.030205
dc.identifier.issn2332-3019
dc.identifier.otherAUT: CRI01087; WWA01535;
dc.identifier.urihttp://hdl.handle.net/10400.1/6661
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherHorizon Research Publishingpor
dc.relation.publisherversionhttp://www.hrpub.org/download/20150620/UJC5-16403908.pdfpor
dc.subjectAtomic quantum statespor
dc.subjectChemical kinetics and reaction dynamicspor
dc.subjectRate Constantpor
dc.titleUsing the reactions O+H2 → OH+H to explore the importance of the atomic quantum states on chemical kinetics and reaction dynamicspor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage85por
oaire.citation.startPage80por
oaire.citation.titleUniversal Journal of Chemistrypor
oaire.citation.volume3por
person.familyNameRio
person.familyNameBrandão
person.familyNameWang
person.givenNameCarolina
person.givenNameJoão
person.givenNameWenli
person.identifier.ciencia-id041C-CEBA-D023
person.identifier.ciencia-id501B-3366-CB7B
person.identifier.ciencia-idFB1F-BEF0-E41B
person.identifier.orcid0000-0001-5018-6542
person.identifier.orcid0000-0003-3047-7793
person.identifier.orcid0000-0003-3313-9511
person.identifier.ridE-2940-2012
person.identifier.ridA-6390-2010
person.identifier.ridE-3358-2012
person.identifier.scopus-author-id6701614002
person.identifier.scopus-author-id7004555284
rcaap.rightsopenAccesspor
rcaap.typearticlepor
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relation.isAuthorOfPublicationc777e448-74ef-4bc6-9ed7-0ff07d1181f9
relation.isAuthorOfPublication.latestForDiscovery0f614a95-b0f9-4be4-9bd1-cd8882c453b0

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