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Compound-specific carbon isotope analysis of short-chain fatty acids from pine tissues: characterizing paleo-fire residues and plant exudates

dc.contributor.authorJambrina-Enríquez, Margarita
dc.contributor.authorde Vera, Caterina Rodríguez
dc.contributor.authorDavara, Javier
dc.contributor.authorHerrera-Herrera, Antonio V.
dc.contributor.authorMallol, Carolina
dc.date.accessioned2023-09-13T09:35:56Z
dc.date.available2023-09-13T09:35:56Z
dc.date.issued2023
dc.description.abstractDifferent types of plant tissues and resin can account for the wax lipids found in sedimentary contexts and archaeological samples. Consequently, there is increasing research to characterize the fatty acid carbon isotope ratios of different plant anatomical parts and their plant exudates (resin). With the aim to explore isotopic differences between plant tissues, state of the fine organic matter, effect of thermal degradation, and to identify plant residues we measured the δ13C values of short-chain fatty acids (δ13C16:0 and δ13C18:0) in: i) dead and fresh (collected and immediately dried) pine needles and branches (Pinus canariensis) and pine resin from laboratory-controlled heating experiments and ii) sediment and charred pine tissue samples from a wild pine forest fire. Our results are compared to previously published experimental open-air fire experiments and pine-fuelled archaeological combustion features. We found that for both fatty acid types, there are differences in δ13C signatures among anatomical parts and initial moisture content. These data allow us to characterize the isotopic signature of pine tissue and the effect of degradation on isotopic biomarkers, as well as to estimate combustion temperatures in pine-fuelled anthropogenic fires.pt_PT
dc.description.sponsorshipGrant project PALEOCHAR – 648871pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.doi10.1007/s12520-023-01815-3pt_PT
dc.identifier.issn1866-9557
dc.identifier.urihttp://hdl.handle.net/10400.1/19970
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherSpringerpt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectOrganic geochemistrypt_PT
dc.subjectLipid biomarkerspt_PT
dc.subjectAnthropogenic combustionpt_PT
dc.subjectOrganic residue analysispt_PT
dc.subjectDegradation of woodpt_PT
dc.subjectBlack layerspt_PT
dc.subjectPine biomarkerspt_PT
dc.subjectPine resinpt_PT
dc.titleCompound-specific carbon isotope analysis of short-chain fatty acids from pine tissues: characterizing paleo-fire residues and plant exudatespt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.issue8pt_PT
oaire.citation.titleArchaeological and Anthropological Sciencespt_PT
oaire.citation.volume15pt_PT
person.familyNameMallol
person.givenNameCarolina
person.identifier.orcid0000-0001-5143-4253
person.identifier.ridH-4652-2015
person.identifier.scopus-author-id22938280200
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication9d9cdc02-b720-497e-87c9-4007f42aa372
relation.isAuthorOfPublication.latestForDiscovery9d9cdc02-b720-497e-87c9-4007f42aa372

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