Mesoporous Ga-MCM-41: a very efficient support for the heterogenisation of metallocene catalysts

Campos, João M.; Lourenço, J. P.; Fernandes, A.; Ribeiro, M. R.

http://hdl.handle.net/10400.1/2059

Utilize este identificador para referenciar este registo.

Nome:	Descrição:	Tamanho:	Formato:
Cat. com. (2008).pdf		198.67 KB	Adobe PDF	Ver/Abrir

Contacte-nos

Autores

Resumo(s)

Mesoporous Ga-containing silicates prepared by direct synthesis, Ga-MCM-41, are used in combination with metallocene Cp2ZrCl2 to provide very effective supported catalysts for ethylene polymerisation. A pre-treatment with methylalumoxane is not required in order to achieve high polymerisation activity levels with these catalysts, whose stability is improved when compared to the case where a purely siliceous support was used for the immobilisation of the metallocene.

Palavras-chave

Ethylene polimerisation GaMCM-41 Zirconocene

URI

http://hdl.handle.net/10400.1/2059

Citação

Campos, J. M.; Lourenço, J. P.; Fernandes, A.; Ribeiro, M.R . Mesoporous Ga-MCM-41: a very efficient support for the heterogenisation of metallocene catalysts, Catalysis Communications, 10, 71-73, 2008.

Editora

Elsevier

Coleções

FCT2-Artigos (em revistas ou actas indexadas)

Ver registo completo