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Shear-induced transitions between a planar lamellar phase and multilamellar vesicles: continuous versus discontinuous transformation

dc.contributor.authorMedronho, B.
dc.contributor.authorShafaei, S.
dc.contributor.authorSzopko, R.
dc.contributor.authorMiguel, M. G.
dc.contributor.authorOlsson, U.
dc.contributor.authorSchmidt, C.
dc.date.accessioned2015-12-02T14:23:38Z
dc.date.available2015-12-02T14:23:38Z
dc.date.issued2008
dc.description.abstractThe shear-induced transitions between an oriented lamellar phase and shear-induced multilamellar vesicles (MLVs) in a nonionic surfactant system were studied by deuterium rheo-NMR spectroscopy as a function of time in start-up experiments at several temperatures and shear rates. By starting from an initial state of oriented lamellae and observing the transformation to the final steady state of MLVs and vice-versa, two different mechanisms were found, depending on the direction of the transition and the initial state. The transition is continuous when MLVs are formed, starting from the oriented lamellar phase. On the other hand, a discontinuous nucleation-and-growth process with a coexistence region is observed when transforming MLVs into an oriented lamellar phase.
dc.identifier.doihttps://dx.doi.org/10.1021/la800326a
dc.identifier.issn0743-7463
dc.identifier.urihttp://hdl.handle.net/10400.1/7255
dc.language.isoeng
dc.peerreviewedyes
dc.publisherAmerican Chemical Society
dc.relation.isbasedonP-003-Y80
dc.titleShear-induced transitions between a planar lamellar phase and multilamellar vesicles: continuous versus discontinuous transformation
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage6486
oaire.citation.startPage6480
oaire.citation.titleLangmuir
oaire.citation.volume24
person.familyNameMedronho
person.givenNameBruno
person.identifier.ciencia-id6918-9AB3-8D22
person.identifier.orcid0000-0003-0972-1739
person.identifier.ridP-5927-2014
person.identifier.scopus-author-id9940656700
rcaap.rightsrestrictedAccess
rcaap.typearticle
relation.isAuthorOfPublication4c03571a-93da-4504-8acf-c74326449852
relation.isAuthorOfPublication.latestForDiscovery4c03571a-93da-4504-8acf-c74326449852

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