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Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry

dc.contributor.authorGabelica, Z.
dc.contributor.authorLouati, A.
dc.contributor.authorBorges, C.
dc.contributor.authorRibeiro, M. F.
dc.contributor.authorLourenço, J. P.
dc.contributor.authorMurphy, D. M.
dc.date.accessioned2012-06-15T14:29:40Z
dc.date.available2012-06-15T14:29:40Z
dc.date.issued2004
dc.date.updated2012-06-14T14:08:07Z
dc.description.abstractCyclic voltammetric experiments of framework Co(II) ions in three different CoAPO structures have provided evidence for a screening effect created by solvent or template molecules which results in a facile oxidation (and a difficult reduction) of the Co(II) ions incorporated into the most open (the less strained) structures. An apparent contradiction of these findings with respect to theoretical expectations is discussed.por
dc.identifier.citationGabeliça, Z.; Louati, A.; Borges, C.; Ribeiro, M.; Lourenço, J. P.; Murphy, D. Evidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetry. In Recent Advances in the Science and Technology of Zeolites and Related Materials Part B. Proceedings of the 14 International Zeolite Conference, 1649-1654, ISBN: 9780444518262. Amsterdam: Elsevier, 2004.por
dc.identifier.isbn9780444518262
dc.identifier.otherAUT: JLO01215;
dc.identifier.urihttp://hdl.handle.net/10400.1/1256
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevierpor
dc.subjectCo incorporationpor
dc.subjectSynthesispor
dc.titleEvidence of a solvent screen effect affecting the redox properties of Co(II) ions in CoAPO-37, CoAPO-40 and CoIST-2 (AEN), by cyclic voltammetrypor
dc.typeconference object
dspace.entity.typePublication
oaire.citation.conferencePlaceAmsterdampor
oaire.citation.endPage1654por
oaire.citation.startPage1649por
oaire.citation.titleRecent Advances in the Science and Technology of Zeolites and Related Materials Part B. Proceedings of the 14 International Zeolite Conferencepor
person.familyNameLourenço
person.givenNameJoão P.
person.identifier634248
person.identifier.ciencia-idF81F-A1F0-2A7C
person.identifier.orcid0000-0002-0501-6672
person.identifier.ridA-7758-2008
person.identifier.scopus-author-id57195730600
rcaap.rightsopenAccesspor
rcaap.typeconferenceObjectpor
relation.isAuthorOfPublicationf66ab886-d989-4c1d-9550-527507723c26
relation.isAuthorOfPublication.latestForDiscoveryf66ab886-d989-4c1d-9550-527507723c26

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