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Chemical ecology of arthropods. 9. Structure and absolute configuration of hippodamine and convergine, two novel alkaloids from american ladybug hippodamia convergens (coleoptera- coccinellidae)

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Tursch, B.
Daloze, D.
Braekman, J. C.
Hootele, C.
Losman, D.
Karlsson, R.

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In a previous communication (2) the isolation of two defensive alkaloid, hippodamine and convergine, from the American ladybug Hippodamia convergens was reported. A preliminary chemical study (2) led to the hypothesis that hippodamine could be represented by (1), with unknown stereochemistry at carbon atom 2. Convergine was supposed to be a 3a or 6a hydroxyhippodamine.

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Pergamon- Elsevier Science, Ltd