Percorrer por autor "Ribeiro, M. Filipa"
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- Catalytic transfer hydrogenation reactions of Glycerol Over Zr-Incorporated Zeolite Beta prepared by a mechanochemical approachPublication . Fernandes, Auguste; Ribeiro, M. Filipa; Lourenço, João P.Zr-containing zeolite beta catalysts were prepared by a post-synthesis procedure involving a dealumination followed by a mechanochemical step and tested in the gas-phase conversion of glycerol. The catalytic data indicate that the catalysts are active in the conversion of glycerol, promoting not only the typical dehydration but also its hydrogenolysis without an external source of hydrogen, resulting in the production of significant amounts of ethylene glycol and methanol. Partially frameworkattached (Si─O)2Zr═O species were identified and are suggested to play an important role in the catalytic behavior of these materials.
- Conversion of glycerol over vanadium supported beta zeolite: role of acidity and alkali cationsPublication . Fernandes, Auguste; Ribeiro, M. Filipa; Lourenço, João P.Different vanadium supported beta zeolites modified with Cs and K, were used as catalysts for the conversion of glycerol, in gas phase, without any external reductant. The catalytic data show that all the catalysts studied are active in the conversion of glycerol and that the presence of vanadium oxide species promotes the formation of allyl alcohol. Moreover, modification of the vanadium-based catalysts with Cs or K changes the vanadium species and puts in evidence the importance of the acidity in this process. A low density of acid sites favors the formation of allyl alcohol, in detriment of acrolein one. The data also indicate that the formation of these compounds is closely related and could be explained using the same mechanistic path.
- Gas-phase conversion of glycerol to allyl alcohol over vanadium-supported zeolite betaPublication . Almeida, Ruben; Ribeiro, M. Filipa; Fernandes, Auguste; Lourenço, João P.Vanadium oxide supported beta zeolite (Si/Al=25, 4% V) was used as catalyst for the one-pass gas-phase conversion of glycerol to allyl alcohol without any external reductant. The catalytic data strongly suggest a consecutive reactions path involving the dehydration to acrolein over the zeolite acid sites followed by a selective reduction through a hydrogen-transfer reaction. Acidity is expected to play a major role in what concerns the selectivity, as demonstrated by the catalytic results obtained by the impregnation of vanadium on a previously Cs-exchanged sample that achieved ca. 30% selectivity to allyl alcohol at ca. 20% glycerol conversion.
- On the characterization and performance of highly dispersed TiO2 nanoparticles onto BEA zeolite in the continuous gas-phase photooxidation of ethylene.Publication . Ferreira, Ricardo; Morales-Torres, Sergio; Pastrana-Martínez, Luisa María; Maldonado Hodar, Francisco Jose; Lourenço, João P.; João, Isabel M.; Silva, João Miguel; Ribeiro, M. Filipa; Fernandes, AugusteTwo series of TiO2-based zeolite composites (BEA structures) were prepared by employing a sol–gel method using two different synthesis approaches, i.e., acidic and basic media. Different photocatalytic composites obtained with increasing amounts of TiO2 (10–50 wt%) were thoroughly characterized and subsequently tested in the photooxidation of ethylene in a continuous gas-phase system. Results showed that sol–gel experimental conditions had a significant effect on the final properties of the samples, as photocatalytic composites obtained under basic conditions showed better TiO2 dispersion and interaction with the BEA support than their counterparts prepared in an acidic medium. The same photocatalysts showed high performance in ethylene photooxidation, demonstrating complete mineralization and results comparable to or even better than those of the bulk TiO2 material.