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- Development of a high-power multilayer PVDF acoustic projector for 40 to 80 kHz bandPublication . Silva, António; Hughes, Ashley; Pozzatti, Daniel; Zabel, Friedrich; Viegas, Rúben; Martins, MarcosA piston type projector using the PVDF piezoelectric polymer was developed for operating in underwater environment, below 100 kHz. For those frequencies PZT piezoelectric ceramic is usually a preferable choice and PVDF is only considered for frequencies above a few hundreds of kHz. This paper will show that efficient underwater acoustic projectors for frequencies below 100 kHz can be implemented regarding an appropriate impedance adapter is being used. The developed project presents a calibrated transmitting voltage response (TVR) of approximately 166, 160 and 175 dB at 40, 50 and 75 kHz, respectively. The PVDF TVR values are compatible with the PZT projectors available on market with the advantage of having a larger bandwidth than most PZT projectors. To the authors knowledge this is the first time that a PVDF projector attain such characteristics. Although theoretically the PVDF projector bandwidth is larger than 40 to 80 kHz, in practice it was observed that only between those frequencies the project presents a stable operation for the transmission of long-term signals.
- Electromechanical actuators based on poly(vinylidene fluoride) with [N-1 (1) (1) (2(OH))][NTf2] and [C(2)mim] [C2SO4]Publication . Dias, J. C.; Martins, Marcos; Ribeiro, S.; Silva, M. M.; Esperança, J. M. S. S.; Ribeiro, C.; Botelho, G.; Costa, C. M.; Lanceros-Mendez, S.Actuators based on electroactive polymers are increasingly used in applications including microelectronic devices and artificial muscles, demanding low voltage operation and controllable switching response. This work reports on the preparation of electroactive actuators based on poly(vinylidene fluoride) (PVDF) composites with 10, 25, and 40 wt% N,N,N-trimethyl-N-(2-hydroxyethyl) ammonium bis(trifluoromethylsulfonyl)imide ([N-1 1 1 2(OH)][NTf2]) and 1-Ethyl-3-methylimidazolium Ethylsulfate ([C(2)mim][C2SO4]) ionic liquids (ILs) prepared by solvent casting. Independent of the IL type, its presence leads to the crystallization of PVDF in the piezoelectric beta-phase. The degree of crystallinity and electrical conductivity of the samples strongly depends on ILs type and content. The highest electrical conductivity was found for PVDF/IL composites with 40 wt% of [N-1 1 1 2(OH)][NTf2]. The strain displacement and bending of the PVDF/IL composites were evaluated as a function of IL type and content under applied peak voltages of 2.0, 5.0, and 10.0 V at a frequency of 10 mHz. Strain displacement of the actuators depends more on IL content than on IL type, and the best strain bending response was found for the PVDF/IL composite with 25 wt% of [N-1 1 1 2(OH)][NTf2] at 5.0 V. Further, it is shown that [C(2)mim] [C2SO4]/PVDF composites do not show cytotoxic behavior, being suitable for biomedical applications.
- Wideband and wide beam polyvinylidene difluoride (PVDF) acoustic transducer for broadband underwater communicationsPublication . Martins, Marcos; Faria, Carlos; Matos, Tiago; Gonçalves, Luís; Cabral, José; Silva, António; Jesus, SergioThe advances in wireless communications are still very limited when intended to be used on Underwater Communication Systems mainly due to the adverse proprieties of the submarine channel to the acoustic and radio frequency (RF) waves propagation. This work describes the development and characterization of a polyvinylidene difluoride ultrasound transducer to be used as an emitter in underwater wireless communications. The transducer has a beam up to 10° × 70° degrees and a usable frequency band up to 1 MHz. The transducer was designed using Finite Elements Methods and compared with real measurements. Pool trials show a transmitting voltage response (TVR) of approximately 150 dB re µPa/V@1 m from 750 kHz to 1 MHz. Sea trials were carried in Ria Formosa, Faro (Portugal) over a 15 m source-receiver communication link. All the signals were successfully detected by cross-correlation using 10 chirp signals between 10 to 900 kHz.
- Erratum: Martins, M.S., et al. Wideband and wIde beam polyvinylidene difluoride (PVDF) acoustic transducer for broadband underwater. Sensors 2019, 19, 3991Publication . Martins, Marcos; Faria, Carlos L.; Matos, Tiago; Gonçalves, L. M.; Cabral, José; Silva, António; Jesus, SergioThe authors wish to make the following erratum to this paper [...].
- Development of a cost-effective optical sensor for continuous monitoring of turbidity and suspended particulate matter in marine environmentPublication . Matos, T.; Faria, C. L.; Martins, Marcos; Henriques, Renato; Gomes, P. A.; Gonçalves, L. M.A cost-effective optical sensor for continuous in-situ monitoring of turbidity and suspended particulate matter concentration (SPM), with a production cost in raw materials less than 20 €, is presented for marine or fluvial applications. The sensor uses an infrared LED and three photodetectors with three different positions related to the light source-135º, 90º and 0º-resulting in three different types of light detection: backscattering, nephelometry and transmitted light, respectively. This design allows monitoring in any type of environment, offering a wide dynamic range and accuracy for low and high turbidity or SPM values. An ultraviolet emitter-receiver pair is also used to differentiate organic and inorganic matter through the differences in absorption at different wavelengths. The optical transducers are built in a watertight structure with a radial configuration where a printed circuit board with the electronic signal coupling is assembled. An in-lab calibration of the sensor was made to establish a relation between suspended particulate matter (SPM) or the turbidity (NTU) to the photodetectors' electrical output value in Volts. Two different sizes of seashore sand were used (180 µm and 350 µm) to evaluate the particle size susceptibility. The sensor was tested in a fluvial environment to evaluate SPM change during sediment transport caused by rain, and a real test of 22 days continuous in-situ monitoring was realized to evaluate its performance in a tidal area. The monitoring results were analysed, showing the SPM change during tidal cycles as well as the influence of the external light and biofouling problems.
- Energy harvesting to supply moored oceanographic monitoring stationsPublication . Faria, C. L.; Martins, Marcos; Lima, R.; Gonçalves, L. M.This work aims to study a new energy harvesting device to be anchored on the ocean floor and convert any type of currents, tides or oscillation movement into electrical energy using linear electromagnetic generators. The final application is to supply energy to a set of moored monitoring sensors that collects data and allowing the system to be energetically autonomous. The proposed setup is a spherical buoy with no external moving parts, to be more biofouling proof. The maximum output power measured for a 4 Hz movement was 9.9 mW with only one linear electromagnetic generator.