Synthesis and characterization of new CoAPSO-40 and ZnAPSO-40 molecular sieves. Influence of the composition on the thermal and hydrothermal stability of AlPO4-40 -based materials

Lourenço, J. P.; Ribeiro, M. F.; Borges, C.; Rocha, J.; Onida, B.; Garrone, E.; Gabelica, Z.

http://hdl.handle.net/10400.1/2053

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Abstract(s)

Highly crystalline CoAPSO-40 and ZnAPSO-40 have been synthesized and characterized by powder XRD, TG/ DSC, SEM, EDX, 27Al, 31P and 29Si solid-state NMR, di use re¯ectance UV±VIS spectroscopy, FT IR and catalytic tests using the m-xylene isomerization and n-heptane cracking as model reactions. The simultaneous incorporation of silicon and a divalent metal in the framework of the AFR structure results in the generation of Brùnsted acid sites similar to those found in SAPO-40 and MeAPO-40. The catalytic activity of the samples for acid catalyzed reactions is higher than that of SAPO-40 with a homogeneous framework silicon distribution. The framework incorporation of cobalt or zinc results in a decrease of the thermal and hydrothermal stability of the metal bearing AFR framework, when compared with AlPO4-40 and SAPO-40.

Keywords

MeAPSO-40 Catalytic activity Thermostability Synthesis Co incorporation Cobalt and zinc incorporation Catalytic activity

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http://hdl.handle.net/10400.1/2053

Citation

Lourenço, J. P.; Ribeiro, M. F.; Borges, C.; Rocha, J.; Onida, B.; Garrone, E.; Gabelica, Z. Synthesis and characterization of new CoAPSO-40 and ZnAPSO-40 molecular sieves. Influence of the composition on the thermal and hydrothermal stability of AlPO4-40 -based materials, Microporous and Mesoporous Materials, 38, 267-278, 2000.