Publication
Photorelease of incarcerated guests in aqueous solution with phenacyl esters as the trigger
| dc.contributor.author | Jagadesan, Pradeepkumar | |
| dc.contributor.author | Silva, José P. da | |
| dc.contributor.author | Givens, Richard S. | |
| dc.contributor.author | Ramamurthy, V. | |
| dc.date.accessioned | 2015-06-22T14:13:50Z | |
| dc.date.available | 2015-06-22T14:13:50Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | We report the clean, efficient photorelease of a series of carboxylic acids embedded in octa acid (OA) host and protected by a p-hydroxyphenacyl cage. A key role is played by the cage by providing hydrophobicity for entry into the OA enclosure and yet readily removable as a photoactivated protecting group for release from the host. The rapid photo-Favorskii rearrangement of the departing chromophore does not react with the host OA but diminishes hydrophobicity of the OA contents, leading to their facile release into the solvent. | |
| dc.identifier.doi | https://dx.doi.org/10.1021/acs.orglett.5b00252 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.uri | http://hdl.handle.net/10400.1/6564 | |
| dc.language.iso | eng | |
| dc.peerreviewed | yes | |
| dc.publisher | American Chemical Society | |
| dc.relation.isbasedon | P-00A-90V | |
| dc.title | Photorelease of incarcerated guests in aqueous solution with phenacyl esters as the trigger | |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 1279 | |
| oaire.citation.issue | 5 | |
| oaire.citation.startPage | 1276 | |
| oaire.citation.title | Organic letters | |
| oaire.citation.volume | 17 | |
| person.familyName | Silva | |
| person.givenName | José Paulo da | |
| person.identifier.ciencia-id | 3413-C4F4-73F7 | |
| person.identifier.orcid | 0000-0002-6458-7328 | |
| person.identifier.rid | A-4606-2008 | |
| person.identifier.scopus-author-id | 7201733236 | |
| rcaap.rights | restrictedAccess | |
| rcaap.type | article | |
| relation.isAuthorOfPublication | e2004fa2-a47d-44b0-b11c-fc95fe51cbf9 | |
| relation.isAuthorOfPublication.latestForDiscovery | e2004fa2-a47d-44b0-b11c-fc95fe51cbf9 |
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