Repository logo
 
Publication

Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids

2016Journal article Restricted access
Simple item page
dc.contributor.authorBruno, Sofia M.
dc.contributor.authorGomes, Ana C.
dc.contributor.authorOliveira, Tânia S. M.
dc.contributor.authorAntunes, Margarida M.
dc.contributor.authorLopes, Andre D.
dc.contributor.authorValente, Anabela A.
dc.contributor.authorGonçalves, Isabel S.
dc.contributor.authorPillinger, Martyn
dc.date.accessioned2017-04-07T15:57:36Z
dc.date.available2017-04-07T15:57:36Z
dc.date.issued2016
dc.description.abstractMetal-free cucurbit[7]uril (CB7) solid-state assemblies promote acid-catalysed alcoholysis of aliphatic and aromatic epoxides under mild conditions to give beta-alkoxy alcohols, which are important intermediates for the synthesis of a vast range of compounds such as bioactive pharmaceuticals. The catalytic process is heterogeneous and the catalyst can be reused in consecutive runs without any reactivation treatment. The acid species responsible for the catalytic activity of CB7 may be entrapped hydronium ions.
dc.description.sponsorshipPOCI-01-0145-FEDER-007679; BPD/UI89/4864/2014
dc.identifier.doi10.1039/c6ob00512h
dc.identifier.issn1477-0520
dc.identifier.otherAUT: ADL01681;
dc.identifier.urihttp://hdl.handle.net/10400.1/9759
dc.language.isoeng
dc.peerreviewedyes
dc.publisherRoyal Society of Chemistry
dc.relationFCOMP-01-0124-FEDER-029779
dc.relation.isbasedonWOS:000374786500004
dc.titleCatalytic alcoholysis of epoxides using metal-free cucurbituril-based solids
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FCTM%2F50011%2F2013/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/COMPETE/PTDC%2FQEQ-SUP%2F1906%2F2012/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F46473%2F2008/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F89068%2F2012/PT
oaire.citation.endPage3877
oaire.citation.issue16
oaire.citation.startPage3873
oaire.citation.titleOrganic and Biomolecular Chemistry
oaire.citation.volume14
oaire.fundingStream5876
oaire.fundingStreamCOMPETE
oaire.fundingStreamSFRH
oaire.fundingStreamSFRH
person.familyNameD. Lopes
person.givenNameAndré
person.identifier2824636
person.identifier.ciencia-id351E-856A-0300
person.identifier.orcid0000-0002-9702-1216
person.identifier.ridE-2136-2012
person.identifier.scopus-author-id7201958625
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsrestrictedAccess
rcaap.typearticle
relation.isAuthorOfPublicationf2f0fe56-e04d-4229-b37b-2b9f1789fe2d
relation.isAuthorOfPublication.latestForDiscoveryf2f0fe56-e04d-4229-b37b-2b9f1789fe2d
relation.isProjectOfPublicationc25bcc3b-270f-40c4-82d9-cd719c5e0e1d
relation.isProjectOfPublication55faf00f-0259-4bf7-9208-2f7e03b0e5d7
relation.isProjectOfPublicationd2a793cc-e153-4f50-a82e-0c3656f659e0
relation.isProjectOfPublicationf0407563-ef69-46e3-9f88-46a23070093f
relation.isProjectOfPublication.latestForDiscoveryc25bcc3b-270f-40c4-82d9-cd719c5e0e1d

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
H.9759.pdf
Size:
728.69 KB
Format:
Adobe Portable Document Format
Download

Collections

FCT2-Artigos (em revistas ou actas indexadas)