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Supercritical water: percolation transitions and a colloidal mesophase
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| 1.25 MB | Adobe PDF |
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A revised phase diagram for water shows three distinct fluid phases. There is no continuity of liquid and gas and no critical point on Gibbs density surface. A liquid state, water, spans all temperatures. A thermodynamic rigidity function, which distinguishes gas and 'liquid, shows a remarkable symmetry between complimentary corresponding states of steam and water.
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Statistical mechanics