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Unusual framework stabilization of Cu(II) and Cu(I) ions in a novel copper-substituted aluminophosphate with AEN topology prepared by one pot synthesis

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Resumo(s)

A novel copper-substituted aluminophosphate (CuIST-2) has been synthesized using methylamine as a templating agent. X-Ray diffraction studies provide evidence for an AEN topology similar to the parent Cu-free IST-2.

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Synthesis

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Gabelica, Z.; Fernandes, A.; Ribeiro, M. F.; Lourenço, J. P.; Valange, S.; Louati, A.; Murphy, D. M. Unusual framework stabilization of Cu(II) and Cu(I) ions in a novel copper-substituted aluminophosphate with AEN topology prepared by one pot synthesis. In From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. Proceedings of the 15 International Zeolite Conference, 185-192, ISBN: 9780444530684. Amsterdam: Elsevier, 2007.

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Elsevier

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