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Reactions of azovinylphosphonates with nucleophilic alkenes and heterocycles: synthesis of Tetrahydropyridazine-3-phosphonate and 2-Substituted-1-hydrazonoethylphosphonate derivatives

dc.contributor.authorLemos, A.
dc.contributor.authorLopes, Marta
dc.date.accessioned2014-12-16T15:10:37Z
dc.date.available2014-12-16T15:10:37Z
dc.date.issued2008
dc.date.updated2014-12-11T11:21:20Z
dc.description.abstractTransient azovinylphosphonates, generated in situ by base induced dehydrohalogenation of the corresponding 2-bromo- and 2-chloro-acetylphosphonate- tertbutoxycarbonyl hydrazones are intercepted by electron rich alkenes and heterocycles in hetero Diels-Alder reactions, producing tetrahydopyridazine-3-phosphonates or open chain α-hydrazono phosphonates.por
dc.identifier.doihttp://dx.doi.org/10.1080/10426500802028393
dc.identifier.issn1042-6507
dc.identifier.otherAUT: ALE01411
dc.identifier.urihttp://hdl.handle.net/10400.1/5690
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherTaylor & Francispor
dc.relation.publisherversionhttp://www.tandfonline.com/doi/full/10.1080/10426500802028393#.VJBIU3uUTp8por
dc.subjectα-hydrazonophosphonatespor
dc.subject3-phosphono-1,2-diaza-1,3-butadienespor
dc.subjectAzovinylphosphonatespor
dc.subjectAddition-eliminationpor
dc.subjectCycloadditionpor
dc.subjectTetrahydropyridazine-3-phosphonatespor
dc.titleReactions of azovinylphosphonates with nucleophilic alkenes and heterocycles: synthesis of Tetrahydropyridazine-3-phosphonate and 2-Substituted-1-hydrazonoethylphosphonate derivativespor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage2890por
oaire.citation.issue11por
oaire.citation.startPage2882por
oaire.citation.titlePhosphorus, Sulfur, and Siliconpor
oaire.citation.volume183por
person.familyNameLemos
person.givenNameAmerico
person.identifier.ciencia-idA81D-6DC7-31E4
person.identifier.orcid0000-0001-9588-4555
person.identifier.ridB-4892-2008
person.identifier.scopus-author-id11139694000
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication70dfe028-027a-4dec-b6e3-1a49c9be9e60
relation.isAuthorOfPublication.latestForDiscovery70dfe028-027a-4dec-b6e3-1a49c9be9e60

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