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To date or not to date? A comparison of different 14C pretreatment methods applied to archeological marine shells from Vale Boi (Portugal)

dc.contributor.authorPaleček, Dragana
dc.contributor.authorFalini, Giuseppe
dc.contributor.authorWacker, Lukas
dc.contributor.authorMannino, Marcello A.
dc.contributor.authorBicho, Nuno
dc.contributor.authorTalamo, Sahra
dc.contributor.authorRombolà, Alessandro G.
dc.contributor.authorFabbri, Daniele
dc.contributor.authorCascalheira, João
dc.date.accessioned2024-11-23T12:54:25Z
dc.date.available2024-11-23T12:54:25Z
dc.date.issued2024-08
dc.description.abstractMollusk shells are often found in archeological sites, given their great preservation potential and high value as a multipurpose resource, and they can often be the only available materials useful for radiocarbon (14C) dating. However, dates obtained from shells are often regarded as less reliable compared to those from bones, wood, or charcoals due to different factors (e.g., Isotope fractionation, reservoir effects etc.). The standard acid etching pretreatment for mollusk shells is the most used in many 14C laboratories, although another protocol known as CarDS (Carbonate Density Separation) was introduced just over a decade ago. We compare these two methods with two newly proposed methods for intracellular organic matrix extraction. We applied all four methods to samples selected from different archeological layers of the well-known Upper Paleolithic site of Vale Boi, rich in mollusk specimens throughout the stratigraphic sequence. Here we compare our results to previous dates to determine which of these pretreatment methods results in the most reliable 14C dates. Based on the results of this study, all four methods gave inconsistent ages compared to previous dates and the stratigraphic attribution.eng
dc.description.sponsorshipDL57/2016/CP1361/CT0026; Grant Number 803147
dc.identifier.doi10.1017/rdc.2024.80
dc.identifier.eissn1945-5755
dc.identifier.issn0033-8222
dc.identifier.urihttp://hdl.handle.net/10400.1/26332
dc.language.isoeng
dc.peerreviewedyes
dc.publisherCambridge University Press
dc.relation.ispartofRadiocarbon
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectChemical Analysis
dc.subjectMollusk Shells
dc.subjectPaleolithic
dc.subjectPretreatment
dc.subjectRadiocarbon AMS Dating
dc.titleTo date or not to date? A comparison of different 14C pretreatment methods applied to archeological marine shells from Vale Boi (Portugal)eng
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage720
oaire.citation.issue4
oaire.citation.startPage699
oaire.citation.titleRadiocarbon
oaire.citation.volume66
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85
person.familyNameBicho
person.familyNameCascalheira
person.givenNameNuno
person.givenNameJoão
person.identifierJ-2841-2012
person.identifier.ciencia-id7619-7089-221C
person.identifier.ciencia-idFD10-4F70-0FF0
person.identifier.orcid0000-0001-9655-0549
person.identifier.orcid0000-0003-0321-8892
person.identifier.ridB-8343-2014
person.identifier.scopus-author-id55069924600
relation.isAuthorOfPublication95e67113-81f2-40a6-939e-615036a18336
relation.isAuthorOfPublication16e1a4d5-55fc-4564-90bb-0fce7b4d3a6d
relation.isAuthorOfPublication.latestForDiscovery95e67113-81f2-40a6-939e-615036a18336

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