Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.1/6559
Título: A latent reaction in a model gfp chromophore revealed upon confinement: photohydroxylation of ortho-halo benzylidene-3-methylimidazolidiones via an electrocylization process
Autor: Samanta, Shampa R.
Silva, José P. da
Baldridge, Anthony
Tolbert, Laren M.
Ramamurthy, V.
Data: 2014
Editora: American Chemical Society
Resumo: Excited state behavior of halogen substituted model GFP chromophores was investigated in an acetonitrile solution and in a confined environment provided by an octa acid capsule in water. Of the ortho, meta, and para halogen substituted GFP chromophores only the ortho compounds gave a new product resulting from an unprecedented photosubstitution of halogens by the hydroxyl group. This unusual reaction highlights the importance of confined spaces in bringing about some unattainable photoreactions.
Peer review: yes
URI: http://hdl.handle.net/10400.1/6559
DOI: https://dx.doi.org/10.1021/ol5013058
ISSN: 1523-7060
Aparece nas colecções:FCT2-Artigos (em revistas ou actas indexadas)



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