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Role of hole injection in electroforming of LiF-polymer memory diodes

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Al/LiF/poly(spirofluorene)/Ba/Al diodes submitted to bias voltages near 15 V undergo a change to a nonvolatile memory known as electroforming. Prior to electroforming, electron trapping occurs, followed by a tunneling current due to electrons from the polymer into LiF. At the onset voltage for electroforming, a sudden electroluminescence burst originating from electronic excitations in the polymer is detected. This confirms that hole injection into the polymer through LiF occurs leading to nonvolatile resistive switching.

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Bory, B.F.; Gomes, H.L.; Janssen, R.A.J.; De Leeuw, D.M.; Meskers, S.C.J.Role of hole injection in electroforming of LiF-polymer memory diodes, Journal of Physical Chemistry C, 116, 23, 12443-12, 2012.

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ACS Publications

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