Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.1/6564
Título: Photorelease of incarcerated guests in aqueous solution with phenacyl esters as the trigger
Autor: Jagadesan, Pradeepkumar
Silva, José P. da
Givens, Richard S.
Ramamurthy, V.
Data: 2015
Editora: American Chemical Society
Resumo: We report the clean, efficient photorelease of a series of carboxylic acids embedded in octa acid (OA) host and protected by a p-hydroxyphenacyl cage. A key role is played by the cage by providing hydrophobicity for entry into the OA enclosure and yet readily removable as a photoactivated protecting group for release from the host. The rapid photo-Favorskii rearrangement of the departing chromophore does not react with the host OA but diminishes hydrophobicity of the OA contents, leading to their facile release into the solvent.
Peer review: yes
URI: http://hdl.handle.net/10400.1/6564
DOI: https://dx.doi.org/10.1021/acs.orglett.5b00252
ISSN: 1523-7060
Aparece nas colecções:FCT2-Artigos (em revistas ou actas indexadas)

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